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Exhibit 5-1 Consider the reaction of Magnesium with oxygen to form magnesium oxide and heat as shown below to answer the following problem(s) : 2 Mg (s) + O2 (g) →2 MgO (s) D H ° rxn = - 1204 kJ -Refer to Exhibit 5-1. How much heat is released when 2.43 grams of Mg (s) reacts at constant pressure? Molar Mass(Mg) = 24.3 g/mol


A) - 602 kJ
B) - 240.8 kJ
C) - 120.4 kJ
D) - 60.2 kJ
E) None of these

F) C) and D)
G) All of the above

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How much heat is required to raise the temperature of 25.0 grams of water from 32.0 ° C to 87.0 ° C? Specific Heat (H2O) = 4.184 J/g × ° C


A) 9.20 J
B) 329 J
C) 3.35×103 J
D) 5.75×103 J
E) 1.05×104 J

F) A) and E)
G) C) and D)

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What is the specific heat of an unknown substance if 25.0 grams of the substance absorbs 77.0 calories of heat and the temperature increases by 5.5 ° C?


A) 0.51 cal/g × ° C
B) 0.513 cal/g × ° C
C) 0.56 cal/g × ° C
D) 0.616 cal/g × ° C
E) 0.62 cal/g × ° C

F) D) and E)
G) C) and E)

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C

Consider the following reaction and its corresponding enthalpy: 2 Mg (s) + O2 (g) →2 MgO (s) D H ° rxn = - 1204 kJ/mol What amount of heat is exchanged when 5.00 grams of magnesium metal reacts at constant pressure?


A) - 124 kJ
B) - 248 kJ
C) - 3.01×103 kJ
D) 7.32×104 kJ
E) 1.44×105 kJ

F) A) and B)
G) A) and C)

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The heat exchange of a certain exothermic reaction is measured in a solution calorimeter. The sign convention for the heat exchanged in this process would be a ____ value for the heat released in the reaction and a ____ value for the heat absorbed by the calorimeter.


A) negative ( - ) , positive (+)
B) positive (+) , negative ( - )
C) negative ( - ) , negative ( - )
D) positive (+) , positive (+)

E) B) and D)
F) B) and C)

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How many joules of heat are necessary to raise the temperature of a 1.42 kg block of copper from 25.0 ° C to 88.5 ° C? (Specific heat of copper = 0.385 J/g × ° C)


A) 234000 J
B) 34700 J
C) 234 J
D) 34.7 J
E) 0.0347 J

F) A) and E)
G) All of the above

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Given the following Thermodynamic data: D H f (Fe2 O3 ; s) = - 822 kJ/mol D H f (FeCl 3 ; s) = - 400 kJ/mol D H f (H₂ O; g) = - 242 kJ/mol D H f (H₂ O; Given the following Thermodynamic data: D H f (Fe<sub>2</sub> O<sub>3</sub> ; s)  = - 822 kJ/mol D H f (FeCl 3 ; s)  = - 400 kJ/mol D H f (H₂ O; g)  = - 242 kJ/mol D H f (H₂ O;   )  = - 286 kJ/mol D H f (HCl; g)  = - 92 kJ/mol D H f (HCl; aq)  = - 167 kJ/mol What is the Standard Molar Enthalpy of Reaction D H rxn for the following reaction? Fe<sub>2</sub> O<sub>3</sub>(s)  + 6 HCl (g)  2 FeCl 3 (s)  + 3 H₂ O (g)  D H rxn = ?? A)  - 1256 kJ/mol B)  - 284 kJ/mol C)  - 152 kJ/mol D)  272 kJ/mol E)  298 kJ/mol ) = - 286 kJ/mol D H f (HCl; g) = - 92 kJ/mol D H f (HCl; aq) = - 167 kJ/mol What is the Standard Molar Enthalpy of Reaction D H rxn for the following reaction? Fe2 O3(s) + 6 HCl (g) 2 FeCl 3 (s) + 3 H₂ O (g) D H rxn = ??


A) - 1256 kJ/mol
B) - 284 kJ/mol
C) - 152 kJ/mol
D) 272 kJ/mol
E) 298 kJ/mol

F) A) and B)
G) B) and E)

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When a 83.0 g sample of a metal at 100.0 ° C is added tO45.0 g of water at 23.25 ° C, the final temperature of both the water and metal is 27.68 ° C. The specific heat of water is 4.184 J/g × K. What is the specific heat of the metal?


A) 10.0 J/g × K
B) 11.5 J/g × K
C) 0.100 J/g × K
D) 0.139 J/g × K
E) none of these

F) A) and B)
G) A) and C)

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Given the data below, what is D H ° for the following reaction? CH4 (g) + 3 Cl2 (g) →CHCl3 (g) + 3 HCl (g) D H ° f [CH4 (g) ] = - 75 kJ/mol D H ° f [CHCl3 (g) ] = - 103 kJ/mol D H ° f [HCl (g) ] = - 92 kJ/mol


A) - 304 kJ
B) - 120 kJ
C) +304 kJ
D) +120 kJ
E) none of these

F) A) and B)
G) C) and D)

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Which of the following reactions absorbs heat from the surroundings in order to proceed to completion? I. CO (g) + 1/2 O2 (g) →CO2 (g) D H rxn = - 283.0 kJ II. Al2O3 (s) →2 Al (s) + 3/2 O2 (g) (endothermic) III. SO3 (g) + 99.2 kJ→S (s) + 3/2 O2 (g)


A) I only
B) I and III
C) I and II
D) II and III
E) All of these

F) A) and B)
G) A) and C)

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When a 50.0 g sample of a metal at 100.0 ° C is added tO60.0 g of water at 25.10 ° C, the final temperature of both the water and metal is 32.81 ° C. The specific heat of water is 4.184 J/g × K. What is the specific heat of the metal?


A) 0.576 J/g × K
B) 1.66 J/g × K
C) 45.0 J/g × K
D) 0.900 J/g × K
E) none of these

F) A) and E)
G) A) and D)

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A

The reaction of 8.00 g of SO2 (g) burns in excess oxygen. 9.85 kJ of heat are released. What is D H for the following thermochemical equation? 2 SO2 (g) + O2 (g) →2 SO3 (g)


A) - 1.58×102 kJ
B) - 78.8 kJ
C) - 39.4 kJ
D) +78.8 kJ
E) none of these

F) A) and D)
G) D) and E)

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When a 2.00 g sample of ammonium nitrate (NH4NO3) dissolves in 48.0 g of water the temperature changes from 26.57 ° C to 23.50 ° C. Assuming the specific heat of the solution is 4.184 J/g × K, what is the enthalpy change for dissolving 2.00 g of ammonium nitrate in water?


A) +616 J
B) +642 J
C) - 642 J
D) - 616 J
E) none of these

F) A) and E)
G) A) and B)

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Which of the following substances is expected to have a standard molar enthalpy of formation D H ° f equal to zero?


A) NaCl (s)
B) H2 (g)
C) HCl (aq)
D) N₂( Which of the following substances is expected to have a standard molar enthalpy of formation D H ° <sub>f</sub> equal to zero? A)  NaCl (s)  B)  H<sub>2</sub> (g)  C)  HCl (aq)  D)  N₂(   )  E)  CO<sub>2</sub> (s) )
E) CO2 (s)

F) A) and E)
G) B) and D)

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How much heat must be removed from a 10.0 g sample of graphite (specific heat = 0.720 J/g × K) to decrease its temperature from 55.00 ° C tO44.00 ° C?


A) 0.720 J
B) 7.20 J
C) 7.92 J
D) 79.2 J
E) none of these

F) B) and C)
G) A) and C)

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What is the final temperature upon mixing 75.0 grams of water held at 45.0 ° C witH₂ 5.0 grams of water held at 90.0 ° C?


A) 11.3 ° C
B) 28.1 ° C
C) 56.3 ° C
D) 67.5 ° C
E) 78.8 ° C

F) A) and E)
G) C) and D)

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A reaction of 3.44 g of H2 (g) and 20.5 g of C (s) yields C3H6 (g) , and the enthalphy change is - 11.6 kJ. What is D H for the following reaction? 3 H2 (g) + 3 C (s) →C3H6 (g)


A) - 20.4 kJ
B) - 11.6 kJ
C) - 31.7 kJ
D) - 61.2 kJ
E) none of these

F) A) and E)
G) A) and D)

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Which unit from those listed below would be the best choice as a unit for the heat capacity of a substance?


A) J
B) J/mol
C) J/g
D) J/ ° C
E) J/g × ° C

F) A) and E)
G) A) and B)

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D

Which of the following defines the heat of formation of Fe2O3 (s) ?


A) 2 Fe (g) + 3 O (g) → Fe2O3 (s)
B) 2 Fe (s) + 3/2 O2 (g) → Fe2O3 (s)
C) 4 Fe (s) + 2 O3 (g) → 2 Fe2O3 (s)
D) 2 Fe (g) + 3 O (g) → Fe2O3 (g)
E) none of these

F) B) and C)
G) B) and E)

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Given the equation below, what is D H for the reaction that converts 6.00 g of H₂ O ( Given the equation below, what is D H for the reaction that converts 6.00 g of H₂ O (   )  into H₂ O₂ (   )  and H₂ (g) ? 2 H₂ O (   )  H₂ O₂ (   )  + H₂ (g)  D H = 384 kJ A)  129 kJ B)  64.0 kJ C)  256 kJ D)  384 kJ E)  none of these ) into H₂ O₂ ( Given the equation below, what is D H for the reaction that converts 6.00 g of H₂ O (   )  into H₂ O₂ (   )  and H₂ (g) ? 2 H₂ O (   )  H₂ O₂ (   )  + H₂ (g)  D H = 384 kJ A)  129 kJ B)  64.0 kJ C)  256 kJ D)  384 kJ E)  none of these ) and H₂ (g) ? 2 H₂ O ( Given the equation below, what is D H for the reaction that converts 6.00 g of H₂ O (   )  into H₂ O₂ (   )  and H₂ (g) ? 2 H₂ O (   )  H₂ O₂ (   )  + H₂ (g)  D H = 384 kJ A)  129 kJ B)  64.0 kJ C)  256 kJ D)  384 kJ E)  none of these ) H₂ O₂ ( Given the equation below, what is D H for the reaction that converts 6.00 g of H₂ O (   )  into H₂ O₂ (   )  and H₂ (g) ? 2 H₂ O (   )  H₂ O₂ (   )  + H₂ (g)  D H = 384 kJ A)  129 kJ B)  64.0 kJ C)  256 kJ D)  384 kJ E)  none of these ) + H₂ (g) D H = 384 kJ


A) 129 kJ
B) 64.0 kJ
C) 256 kJ
D) 384 kJ
E) none of these

F) C) and D)
G) None of the above

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